This article is about the electronic device. For specific use in lighting, see LED lamp
"LED" redirects here. For other uses, see LED (disambiguation)
Parts of a conventional LED. The flat bottom surfaces of the anvil and post embedded inside the epoxy act as anchors, to prevent the conductors from being forcefully pulled out via mechanical strain or vibration. Close-up of an LED with the voltage being increased and decreased to show a detailed view of its operationA light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (corresponding to the energy of the photons) is determined by the energy required for electrons to cross the band gap of the semiconductor.[5] White light is obtained by using multiple semiconductors or a layer of light-emitting phosphor on the semiconductor device.[6]
Appearing as practical electronic components in 1962, the earliest LEDs emitted low-intensity infrared (IR) light.[7] Infrared LEDs are used in remote-control circuits, such as those used with a wide variety of consumer electronics. The first visible-light LEDs were of low intensity and limited to red.
Early LEDs were often used as indicator lamps, replacing small incandescent bulbs, and in seven-segment displays. Later developments produced LEDs available in visible, ultraviolet (UV), and infrared wavelengths with high, low, or intermediate light output, for instance, white LEDs suitable for room and outdoor lighting. LEDs have also given rise to new types of displays and sensors, while their high switching rates are useful in advanced communications technology with applications as diverse as aviation lighting, fairy lights, strip lights, automotive headlamps, advertising, general lighting, traffic signals, camera flashes, lighted wallpaper, horticultural grow lights, and medical devices.[8]
LEDs have many advantages over incandescent light sources, including lower power consumption, a longer lifetime, improved physical robustness, smaller sizes, and faster switching. In exchange for these generally favorable attributes, disadvantages of LEDs include electrical limitations to low voltage and generally to DC (not AC) power, the inability to provide steady illumination from a pulsing DC or an AC electrical supply source, and a lesser maximum operating temperature and storage temperature.
LEDs are transducers of electricity into light. They operate in reverse of photodiodes, which convert light into electricity.
History
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Discoveries and early devices
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Green electroluminescence from a point contact on a crystal of SiC recreates Round's original experiment from 1907. Close-up of a 1 watt red power ledElectroluminescence as a phenomenon was discovered in 1907 by the English experimenter H. J. Round of Marconi Labs, using a crystal of silicon carbide and a cat's-whisker detector.[9][10] Russian inventor Oleg Losev reported the creation of the first LED in 1927.[11] His research was distributed in Soviet, German and British scientific journals, but no practical use was made of the discovery for several decades, partly due to the very inefficient light-producing properties of silicon carbide, the semiconductor Losev used.[12][13]
0603 SMD (Surface Mount Device) package LEDIn 1936, Georges Destriau observed that electroluminescence could be produced when zinc sulphide (ZnS) powder is suspended in an insulator and an alternating electrical field is applied to it. In his publications, Destriau often referred to luminescence as Losev-Light. Destriau worked in the laboratories of Madame Marie Curie, also an early pioneer in the field of luminescence with research on radium.[14][15]
Hungarian Zoltán Bay together with György Szigeti pre-empted LED lighting in Hungary in 1939 by patenting a lighting device based on silicon carbide, with an option on boron carbide, that emitted white, yellowish white, or greenish white depending on impurities present.[16] Kurt Lehovec, Carl Accardo, and Edward Jamgochian explained these first LEDs in 1951 using an apparatus employing SiC crystals with a current source of a battery or a pulse generator and with a comparison to a variant, pure, crystal in 1953.[17][18]
Rubin Braunstein[19] of the Radio Corporation of America reported on infrared emission from gallium arsenide (GaAs) and other semiconductor alloys in 1955.[20] Braunstein observed infrared emission generated by simple diode structures using gallium antimonide (GaSb), GaAs, indium phosphide (InP), and silicon-germanium (SiGe) alloys at room temperature and at 77 kelvins. In 1957, Braunstein further demonstrated that the rudimentary devices could be used for non-radio communication across a short distance. As noted by Kroemer[21] Braunstein "…had set up a simple optical communications link: Music emerging from a record player was used via suitable electronics to modulate the forward current of a GaAs diode. The emitted light was detected by a PbS diode some distance away. This signal was fed into an audio amplifier and played back by a loudspeaker. Intercepting the beam stopped the music. We had a great deal of fun playing with this setup." This setup presaged the use of LEDs for optical communication applications.
A 1962 Texas Instruments SNX-100 GaAs LED contained in a TO-18 transistor metal caseIn September 1961, while working at Texas Instruments in Dallas, Texas, James R. Biard and Gary Pittman discovered near-infrared (900 nm) light emission from a tunnel diode they had constructed on a GaAs substrate.[7] By October 1961, they had demonstrated efficient light emission and signal coupling between a GaAs p-n junction light emitter and an electrically isolated semiconductor photodetector.[22] On August 8, 1962, Biard and Pittman filed a patent titled "Semiconductor Radiant Diode" based on their findings, which described a zinc-diffused p–n junction LED with a spaced cathode contact to allow for efficient emission of infrared light under forward bias. After establishing the priority of their work based on engineering notebooks predating submissions from G.E. Labs, RCA Research Labs, IBM Research Labs, Bell Labs, and Lincoln Lab at MIT, the U.S. patent office issued the two inventors the patent for the GaAs infrared light-emitting diode (U.S. Patent US3293513), the first practical LED.[7] Immediately after filing the patent, Texas Instruments (TI) began a project to manufacture infrared diodes. In October 1962, TI announced the first commercial LED product (the SNX-100), which employed a pure GaAs crystal to emit an 890 nm light output.[7] In October 1963, TI announced the first commercial hemispherical LED, the SNX-110.[23]
In the 1960s, several laboratories focused on LEDs that would emit visible light. A particularly important device was demonstrated by Nick Holonyak on October 9, 1962, while he was working for General Electric in Syracuse, New York. The device used the semiconducting alloy gallium phosphide arsenide (GaAsP). It was the first semiconductor laser to emit visible light, albeit at low temperatures. At room temperature it still functioned as a red light-emitting diode. GaAsP was the basis for the first wave of commercial LEDs emitting visible light. It was mass produced by the Monsanto and Hewlett-Packard companies and used widely for displays in calculators and wrist watches.[24][25][26]
0603 SMD (Surface Mount Device) package red LEDM. George Craford,[27] a former graduate student of Holonyak, invented the first yellow LED and improved the brightness of red and red-orange LEDs by a factor of ten in 1972.[28] In 1976, T. P. Pearsall designed the first high-brightness, high-efficiency LEDs for optical fiber telecommunications by inventing new semiconductor materials specifically adapted to optical fiber transmission wavelengths.[29]
Close-up of Red LEDInitial commercial development
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LED display of a TI-30 scientific calculator (c.1978
), which uses plastic lenses to increase the visible digit size X-Ray of a 1970s 8-digit LED calculator displayUntil 1968, visible and infrared LEDs were extremely costly, on the order of US$200 per unit, and so had little practical use.[30] The first commercial visible-wavelength LEDs used GaAsP semiconductors and were commonly used as replacements for incandescent and neon indicator lamps, and in seven-segment displays, first in expensive equipment such as laboratory and electronics test equipment, then later in such appliances as calculators, TVs, radios, telephones, as well as watches.[31]
The Hewlett-Packard company (HP) was engaged in research and development (R&D) on practical LEDs between 1962 and 1968, by a research team under Howard C. Borden, Gerald P. Pighini at HP Associates and HP Labs.[32] During this time HP collaborated with Monsanto Company on developing the first usable LED products.[33] The first usable LED products were HP's LED display and Monsanto's LED indicator lamp, both launched in 1968.[33]
Monsanto was the first organization to mass-produce visible LEDs, using Gallium arsenide phosphide (GaAsP) in 1968 to produce red LEDs suitable for indicators.[30] Monsanto had previously offered to supply HP with GaAsP, but HP decided to grow its own GaAsP.[30] In February 1969, Hewlett-Packard introduced the HP Model 5082-7000 Numeric Indicator, the first LED device to use integrated circuit (integrated LED circuit) technology.[32] It was the first intelligent LED display, and was a revolution in digital display technology, replacing the Nixie tube and becoming the basis for later LED displays.[34]
In the 1970s, commercially successful LED devices at less than five cents each were produced by Fairchild Optoelectronics. These devices employed compound semiconductor chips fabricated with the planar process (developed by Jean Hoerni,[35][36] ). The combination of planar processing for chip fabrication and innovative packaging methods enabled the team at Fairchild led by optoelectronics pioneer Thomas Brandt to achieve the needed cost reductions.[37] LED producers continue to use these methods.[38]
The early red LEDs were bright enough for use as indicators, as the light output was not enough to illuminate an area. Readouts in calculators were so small that plastic lenses were built over each digit to make them legible. Later, other colors became widely available and appeared in appliances and equipment.
Early LEDs were packaged in metal cases similar to those of transistors, with a glass window or lens to let the light out. Modern indicator LEDs are packed in transparent molded plastic cases, tubular or rectangular in shape, and often tinted to match the device color. Infrared devices may be dyed, to block visible light. More complex packages have been adapted for efficient heat dissipation in high-power LEDs. Surface-mounted LEDs further reduce the package size. LEDs intended for use with fiber optics cables may be provided with an optical connector.
Blue LED
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The first blue-violet LED using magnesium-doped gallium nitride was made at Stanford University in 1972 by Herb Maruska and Wally Rhines, doctoral students in materials science and engineering.[39][40] At the time Maruska was on leave from RCA Laboratories, where he collaborated with Jacques Pankove on related work. In 1971, the year after Maruska left for Stanford, his RCA colleagues Pankove and Ed Miller demonstrated the first blue electroluminescence from zinc-doped gallium nitride, though the subsequent device Pankove and Miller built, the first actual gallium nitride light-emitting diode, emitted green light.[41][42] In 1974 the U.S. Patent Office awarded Maruska, Rhines, and Stanford professor David Stevenson a patent for their work in 1972 (U.S. Patent US3819974 A). Today, magnesium-doping of gallium nitride remains the basis for all commercial blue LEDs and laser diodes. In the early 1970s, these devices were too dim for practical use, and research into gallium nitride devices slowed.
In August 1989, Cree introduced the first commercially available blue LED based on the indirect bandgap semiconductor, silicon carbide (SiC).[43] SiC LEDs had very low efficiency, no more than about 0.03%, but did emit in the blue portion of the visible light spectrum.[44][45]
In the late 1980s, key breakthroughs in GaN epitaxial growth and p-type doping[46] ushered in the modern era of GaN-based optoelectronic devices. Building upon this foundation, Theodore Moustakas at Boston University patented a method for producing high-brightness blue LEDs using a new two-step process in 1991.[47] In 2015, a US court ruled that three Taiwanese companies had infringed Moustakas's prior patent, and ordered them to pay licensing fees of not less than US$13 million.[48]
Shuji Nakamura in 2015, with a blue LEDTwo years later, in 1993, high-brightness blue LEDs were demonstrated by Shuji Nakamura of Nichia Corporation using a gallium nitride (GaN) growth process.[49][50][51] These LEDs had efficiencies of 10%.[52] In parallel, Isamu Akasaki and Hiroshi Amano of Nagoya University were working on developing the important GaN deposition on sapphire substrates and the demonstration of p-type doping of GaN. This new development revolutionized LED lighting, making high-power blue light sources practical, leading to the development of technologies like Blu-ray.[53][54]
Nakamura was awarded the 2006 Millennium Technology Prize for his invention.[55] Nakamura, Hiroshi Amano, and Isamu Akasaki were awarded the Nobel Prize in Physics in 2014 for "the invention of efficient blue light-emitting diodes, which has enabled bright and energy-saving white light sources."[56]
In 1995, Alberto Barbieri at the Cardiff University Laboratory (GB) investigated the efficiency and reliability of high-brightness LEDs and demonstrated a "transparent contact" LED using indium tin oxide (ITO) on (AlGaInP/GaAs).
In 2001[57] and 2002,[58] processes for growing gallium nitride (GaN) LEDs on silicon were successfully demonstrated. In January 2012, Osram demonstrated high-power InGaN LEDs grown on silicon substrates commercially,[59] and GaN-on-silicon LEDs are in production at Plessey Semiconductors. As of 2017, some manufacturers are using SiC as the substrate for LED production, but sapphire is more common, as it has the most similar properties to that of gallium nitride, reducing the need for patterning the sapphire wafer (patterned wafers are known as epi wafers). Samsung, the University of Cambridge, and Toshiba are performing research into GaN on Si LEDs. Toshiba has stopped research, possibly due to low yields.[60][61][62][63][64][65][66] Some opt for epitaxy, which is difficult on silicon, while others, like the University of Cambridge, choose a multi-layer structure, in order to reduce (crystal) lattice mismatch and different thermal expansion ratios, to avoid cracking of the LED chip at high temperatures (e.g. during manufacturing), reduce heat generation and increase luminous efficiency. Sapphire substrate patterning can be carried out with nanoimprint lithography.[67][68][69][70][71][72][73]
GaN-on-Si is difficult but desirable since it takes advantage of existing semiconductor manufacturing infrastructure. It allows for the wafer-level packaging of LED dies resulting in extremely small LED packages.[74]
GaN is often deposited using Metalorganic vapor-phase epitaxy (MOCVD),[75] and it also utilizes Lift-off.
White LEDs and the illumination breakthrough
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Even though white light can be created using individual red, green and blue LEDs, this results in poor color rendering, since only three narrow bands of wavelengths of light are being emitted. The attainment of high efficiency blue LEDs was quickly followed by the development of the first white LED. In this device a Y
3Al
5O
12:Ce (known as "YAG" or Ce:YAG phosphor) cerium-doped phosphor coating produces yellow light through fluorescence. The combination of that yellow with remaining blue light appears white to the eye. Using different phosphors produces green and red light through fluorescence. The resulting mixture of red, green and blue is perceived as white light, with improved color rendering compared to wavelengths from the blue LED/YAG phosphor combination.[76]
The first white LEDs were expensive and inefficient. The light output then increased exponentially. The latest research and development has been propagated by Japanese manufacturers such as Panasonic, and Nichia, and by Korean and Chinese manufacturers such as Samsung, Solstice, Kingsun, Hoyol and others. This trend in increased output has been called Haitz's law after Roland Haitz.[77][78]
Light output and efficiency of blue and near-ultraviolet LEDs rose and the cost of reliable devices fell. This led to relatively high-power white-light LEDs for illumination, which are replacing incandescent and fluorescent lighting.[79][80]
Experimental white LEDs were demonstrated in 2014 to produce 303 lumens per watt of electricity (lm/W); some can last up to 100,000 hours.[81][82] Commercially available LEDs have an efficiency of up to 223 lm/W as of 2018.[83][84][85] A previous record of 135 lm/W was achieved by Nichia in 2010.[86] Compared to incandescent bulbs, this is a huge increase in electrical efficiency, and even though LEDs are more expensive to purchase, overall lifetime cost is significantly cheaper than that of incandescent bulbs.[87]
The LED chip is encapsulated inside a small, plastic, white mold[88][89] although sometimes an LED package can incorporate a reflector.[90] It can be encapsulated using resin (polyurethane-based), silicone,[91][92][93] or epoxy[94] containing (powdered) Cerium-doped YAG phosphor particles.[95] The viscosity of phosphor-silicon mixtures must be carefully controlled.[96] After application of a phosphor-silicon mixture on the LED using techniques such as jet dispensing,[97] and allowing the solvents to evaporate, the LEDs are often tested, and placed on tapes for SMT placement equipment for use in LED light bulb production. Some "remote phosphor" LED light bulbs use a single plastic cover with YAG phosphor for one[98] or several blue LEDs, instead of using phosphor coatings on single-chip white LEDs.[99] Ce:YAG phosphors and epoxy in LEDs[100] can degrade with use, and is more apparent with higher concentrations of Ce:YAG in phosphor-silicone mixtures, because the Ce:YAG decomposes with use.[101][102][103] The output of LEDs can shift to yellow over time due to degradation of the silicone.[104] There are several variants of Ce:YAG, and manufacturers in many cases do not reveal the exact compoosition of their Ce:YAG offerings.[105] Several other phosphors are available for phosphor-converted LEDs to produce several colors such as red, which uses nitrosilicate phosphors,[106][107] and many other kinds of phosphor materials exist for LEDs such as phosphors based on oxides, oxynitrides, oxyhalides, halides, nitrides, sulfides, quantum dots, and inorganic-organic hybrid semiconductors. A single LED can have several phosphors at the same time.[108][109] Some LEDs use phosphors made of glass-ceramic or composite phosphor/glass materials.[110][111] Alternatively, the LED chips themselves can be coated with a thin coating of phosphor-containing material, called a conformal coating.[112][113]
The temperature of the phosphor during operation and how it is applied limits the size of an LED die. Wafer-level packaged white LEDs allow for extremely small LEDs.[74]
Physics of light production and emission
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In a light-emitting diode, the recombination of electrons and electron holes in a semiconductor produces light (be it infrared, visible or UV), a process called "electroluminescence". The wavelength of the light depends on the energy band gap of the semiconductors used. Since these materials have a high index of refraction, design features of the devices such as special optical coatings and die shape are required to efficiently emit light.[114]
Unlike a laser, the light emitted from an LED is neither spectrally coherent nor even highly monochromatic. Its spectrum is sufficiently narrow that it appears to the human eye as a pure (saturated) color.[115][116] Also unlike most lasers, its radiation is not spatially coherent, so it cannot approach the very high intensity characteristic of lasers.
Single-color LEDs
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By selection of different semiconductor materials, single-color LEDs can be made that emit light in a narrow band of wavelengths from near-infrared through the visible spectrum and into the ultraviolet range. As the wavelengths become shorter, because of the larger band gap of these semiconductors, the operating voltage of the LED increases.
Blue LEDs have an active region consisting of one or more InGaN quantum wells sandwiched between thicker layers of GaN, called cladding layers. By varying the relative In/Ga fraction in the InGaN quantum wells, the light emission can in theory be varied from violet to amber.
Aluminium gallium nitride (AlGaN) of varying Al/Ga fraction can be used to manufacture the cladding and quantum well layers for ultraviolet LEDs, but these devices have not yet reached the level of efficiency and technological maturity of InGaN/GaN blue/green devices. If unalloyed GaN is used in this case to form the active quantum well layers, the device emits near-ultraviolet light with a peak wavelength centred around 365 nm. Green LEDs manufactured from the InGaN/GaN system are far more efficient and brighter than green LEDs produced with non-nitride material systems, but practical devices still exhibit efficiency too low for high-brightness applications.[citation needed]
With AlGaN and AlGaInN, even shorter wavelengths are achievable. Near-UV emitters at wavelengths around 360–395 nm are already cheap and often encountered, for example, as black light lamp replacements for inspection of anti-counterfeiting UV watermarks in documents and bank notes, and for UV curing. Substantially more expensive, shorter-wavelength diodes are commercially available for wavelengths down to 240 nm.[117] As the photosensitivity of microorganisms approximately matches the absorption spectrum of DNA, with a peak at about 260 nm, UV LED emitting at 250–270 nm are expected in prospective disinfection and sterilization devices. Recent research has shown that commercially available UVA LEDs (365 nm) are already effective disinfection and sterilization devices.[118] UV-C wavelengths were obtained in laboratories using aluminium nitride (210 nm),[119] boron nitride (215 nm)[120][121] and diamond (235 nm).[122]
White LEDs
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There are two primary ways of producing white light-emitting diodes. One is to use individual LEDs that emit three primary colors—red, green and blue—and then mix all the colors to form white light. The other is to use a phosphor material to convert monochromatic light from a blue or UV LED to broad-spectrum white light, similar to a fluorescent lamp. The yellow phosphor is cerium-doped YAG crystals suspended in the package or coated on the LED. This YAG phosphor causes white LEDs to appear yellow when off, and the space between the crystals allow some blue light to pass through in LEDs with partial phosphor conversion. Alternatively, white LEDs may use other phosphors like manganese(IV)-doped potassium fluorosilicate (PFS) or other engineered phosphors. PFS assists in red light generation, and is used in conjunction with conventional Ce:YAG phosphor. In LEDs with PFS phosphor, some blue light passes through the phosphors, the Ce:YAG phosphor converts blue light to green and red (yellow) light, and the PFS phosphor converts blue light to red light. The color, emission spectrum or color temperature of white phosphor converted and other phosphor converted LEDs can be controlled by changing the concentration of several phosphors that form a phosphor blend used in an LED package.[123][124][125][126]
The 'whiteness' of the light produced is engineered to suit the human eye. Because of metamerism, it is possible to have quite different spectra that appear white. The appearance of objects illuminated by that light may vary as the spectrum varies. This is the issue of color rendition, quite separate from color temperature. An orange or cyan object could appear with the wrong color and much darker as the LED or phosphor does not emit the wavelength it reflects. The best color rendition LEDs use a mix of phosphors, resulting in less efficiency and better color rendering.[citation needed]
The first white light-emitting diodes (LEDs) were offered for sale in the autumn of 1996.[127] Nichia made some of the first white LEDs which were based on blue LEDs with Ce:YAG phosphor.[128] Ce:YAG is often grown using the Czochralski method.[129]
RGB systems
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Combined spectral curves for blue, yellow-green, and high-brightness red solid-state semiconductor LEDs. FWHM spectral bandwidth is approximately 24–27 nm for all three colors. An RGB LED projecting red, green, and blue onto a surfaceMixing red, green, and blue sources to produce white light needs electronic circuits to control the blending of the colors. Since LEDs have slightly different emission patterns, the color balance may change depending on the angle of view, even if the RGB sources are in a single package, so RGB diodes are seldom used to produce white lighting. Nonetheless, this method has many applications because of the flexibility of mixing different colors,[130] and in principle, this mechanism also has higher quantum efficiency in producing white light.[131]
There are several types of multicolor white LEDs: di-, tri-, and tetrachromatic white LEDs. Several key factors that play among these different methods include color stability, color rendering capability, and luminous efficacy. Often, higher efficiency means lower color rendering, presenting a trade-off between the luminous efficacy and color rendering. For example, the dichromatic white LEDs have the best luminous efficacy (120 lm/W), but the lowest color rendering capability. Although tetrachromatic white LEDs have excellent color rendering capability, they often have poor luminous efficacy. Trichromatic white LEDs are in between, having both good luminous efficacy (>70 lm/W) and fair color rendering capability.[132]
One of the challenges is the development of more efficient green LEDs. The theoretical maximum for green LEDs is 683 lumens per watt but as of 2010 few green LEDs exceed even 100 lumens per watt. The blue and red LEDs approach their theoretical limits.[citation needed]
Multicolor LEDs offer a means to form light of different colors. Most perceivable colors can be formed by mixing different amounts of three primary colors. This allows precise dynamic color control. Their emission power decays exponentially with rising temperature,[133] resulting in a substantial change in color stability. Such problems inhibit industrial use. Multicolor LEDs without phosphors cannot provide good color rendering because each LED is a narrowband source. LEDs without phosphor, while a poorer solution for general lighting, are the best solution for displays, either backlight of LCD, or direct LED based pixels.
Dimming a multicolor LED source to match the characteristics of incandescent lamps is difficult because manufacturing variations, age, and temperature change the actual color value output. To emulate the appearance of dimming incandescent lamps may require a feedback system with color sensor to actively monitor and control the color.[134]
Phosphor-based LEDs
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Spectrum of a white LED showing blue light directly emitted by the GaN-based LED (peak at about 465 nm) and the more broadband Stokes-shifted light emitted by the Ce3+:YAG phosphor, which emits at roughly 500–700 nmThis method involves coating LEDs of one color (mostly blue LEDs made of InGaN) with phosphors of different colors to form white light; the resultant LEDs are called phosphor-based or phosphor-converted white LEDs (pcLEDs).[135] A fraction of the blue light undergoes the Stokes shift, which transforms it from shorter wavelengths to longer. Depending on the original LED's color, various color phosphors are used. Using several phosphor layers of distinct colors broadens the emitted spectrum, effectively raising the color rendering index (CRI).[136]
Phosphor-based LEDs have efficiency losses due to heat loss from the Stokes shift and also other phosphor-related issues. Their luminous efficacies compared to normal LEDs depend on the spectral distribution of the resultant light output and the original wavelength of the LED itself. For example, the luminous efficacy of a typical YAG yellow phosphor based white LED ranges from 3 to 5 times the luminous efficacy of the original blue LED because of the human eye's greater sensitivity to yellow than to blue (as modeled in the luminosity function). Due to the simplicity of manufacturing, the phosphor method is still the most popular method for making high-intensity white LEDs. The design and production of a light source or light fixture using a monochrome emitter with phosphor conversion is simpler and cheaper than a complex RGB system, and the majority of high-intensity white LEDs presently on the market are manufactured using phosphor light conversion.[citation needed]
1 watt 9 volt three chips SMD phosphor based white LEDAmong the challenges being faced to improve the efficiency of LED-based white light sources is the development of more efficient phosphors. As of 2010, the most efficient yellow phosphor is still the YAG phosphor, with less than 10% Stokes shift loss. Losses attributable to internal optical losses due to re-absorption in the LED chip and in the LED packaging itself account typically for another 10% to 30% of efficiency loss. Currently, in the area of phosphor LED development, much effort is being spent on optimizing these devices to higher light output and higher operation temperatures. For instance, the efficiency can be raised by adapting better package design or by using a more suitable type of phosphor. Conformal coating process is frequently used to address the issue of varying phosphor thickness.[citation needed]
Some phosphor-based white LEDs encapsulate InGaN blue LEDs inside phosphor-coated epoxy. Alternatively, the LED might be paired with a remote phosphor, a preformed polycarbonate piece coated with the phosphor material. Remote phosphors provide more diffuse light, which is desirable for many applications. Remote phosphor designs are also more tolerant of variations in the LED emissions spectrum. A common yellow phosphor material is cerium-doped yttrium aluminium garnet (Ce3+:YAG).[citation needed]
White LEDs can also be made by coating near-ultraviolet (NUV) LEDs with a mixture of high-efficiency europium-based phosphors that emit red and blue, plus copper and aluminium-doped zinc sulfide (ZnS:Cu, Al) that emits green. This is a method analogous to the way fluorescent lamps work. This method is less efficient than blue LEDs with YAG:Ce phosphor, as the Stokes shift is larger, so more energy is converted to heat, but yields light with better spectral characteristics, which render color better. Due to the higher radiative output of the ultraviolet LEDs than of the blue ones, both methods offer comparable brightness. A concern is that UV light may leak from a malfunctioning light source and cause harm to human eyes or skin.[citation needed]
A new style of wafers composed of gallium-nitride-on-silicon (GaN-on-Si) is being used to produce white LEDs using 200-mm silicon wafers. This avoids the typical costly sapphire substrate in relatively small 100- or 150-mm wafer sizes.[137] The sapphire apparatus must be coupled with a mirror-like collector to reflect light that would otherwise be wasted. It was predicted that since 2020, 40% of all GaN LEDs are made with GaN-on-Si. Manufacturing large sapphire material is difficult, while large silicon material is cheaper and more abundant. LED companies shifting from using sapphire to silicon should be a minimal investment.[138]
Mixed white LEDs
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Tunable white LED array in a floodlightThere are RGBW LEDs that combine RGB units with a phosphor white LED on the market. Doing so retains the extremely tunable color of RGB LED, but allows color rendering and efficiency to be optimized when a color close to white is selected.[139]
Some phosphor white LED units are "tunable white", blending two extremes of color temperatures (commonly 2700K and 6500K) to produce intermediate values. This feature allows users to change the lighting to suit the current use of a multifunction room.[140] As illustrated by a straight line on the chromaticity diagram, simple two-white blends will have a pink bias, becoming most severe in the middle. A small amount of green light, provided by another LED, could correct the problem.[141] Some products are RGBWW, i.e. RGBW with tunable white.[142]
A final class of white LED with mixed light is dim-to-warm. These are ordinary 2700K white LED bulbs with a small red LED that turns on when the bulb is dimmed. Doing so makes the color warmer, emulating an incandescent light bulb.[142]
Other white LEDs
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Another method used to produce experimental white light LEDs used no phosphors at all and was based on homoepitaxially grown zinc selenide (ZnSe) on a ZnSe substrate that simultaneously emitted blue light from its active region and yellow light from the substrate.[143]
Organic light-emitting diodes (OLEDs)
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In an organic light-emitting diode (OLED), the electroluminescent material composing the emissive layer of the diode is an organic compound. The organic material is electrically conductive due to the delocalization of pi electrons caused by conjugation over all or part of the molecule, and the material therefore functions as an organic semiconductor.[144] The organic materials can be small organic molecules in a crystalline phase, or polymers.[145]
The potential advantages of OLEDs include thin, low-cost displays with a low driving voltage, wide viewing angle, and high contrast and color gamut.[146] Polymer LEDs have the added benefit of printable and flexible displays.[147][148][149] OLEDs have been used to make visual displays for portable electronic devices such as cellphones, digital cameras, lighting and televisions.[145][146]
Perovskite Light-emitting diodes (PeLEDs)
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Perovskite light-emitting diodes (PeLEDs) have emerged as promising candidates for next-generation display and lighting technologies. In recent years, researchers have shown a growing interest in perovskite light-emitting diodes (PeLEDs) owing to their capacity for emitting light with narrow bandwidth, adjustable spectrum, ability to deliver high color purity, and cost-effective solution fabrication.[150][151]
Green PeLEDs
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When it comes to efficiency, PeLEDs have not surpassed commercial organic light-emitting diodes (OLEDs) because specific critical parameters, such as charge carrier transport and optical output coupling efficiency, have not been thoroughly optimized.[151]
In response to this challenge, the development of ultra-efficient green PeLEDs with a external quantum efficiency (EQE) exceeding the remarkable 30% milestone was reported by Bai and his colleagues on May 29, 2023.[151] This achievement was made by strategic adjustments in charge carrier transport and the distribution of near-field light. These optimizations effectively reduced electron leakage and resulted in an exceptional light output coupling efficiency of 41.82%. A Ni0.9Mg0.1Ox film with high refractive index and increased hole carrier mobility was used as a hole injection layer to balance charge carrier injection, and a polyethylene glycol layer was inserted between the hole transport layer and the perovskite emission layer to prevent electron leakage and minimize photon loss.[151]
The modified structure of green PeLED enabled it to achieve a world-record external quantum efficiency of 30.84% (with a mean of 29.05 ± 0.77%) at a brightness level of 6514 cd/m2. This pioneering work introduces a compelling approach to building ultra-efficient PeLEDs by effectively balancing electron-hole recombination and enhancing light outcoupling.[151]
However, expanding the effective area of perovskite LEDs can lead to a significant drop in their performance. To address this issue, Sun et.al[152] introduced L-methionine (NVAL) to construct an intermediate phase with low formation enthalpy and COO- coordination. This new intermediate phase altered the crystallization pathway, effectively inhibiting phase segregation. Consequently, high-quality large-area quasi-2D perovskite films were achieved. They further fine-tuned the film's composite dynamics, leading to high-efficiency quasi-2D perovskite green LEDs with an effective area of 9.0 cm2. An external quantum efficiency (EQE) of 16.4% was attained at <n> = 3, making it the most efficient large-area perovskite LED. Moreover, a luminance of 9.1×104 cd/m2 was achieved in the <n> = 10 films.[152]
Blue PeLEDs
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On March 16, 2023, Zhou et al.[153] published a study demonstrating their successful control of ion behavior to create highly efficient sky-blue perovskite light-emitting diodes. They achieved this by utilizing a bifunctional passivator, which consisted of Lewis base benzoic acid anions and alkali metal cations. This passivator had a dual role: it effectively passivated the deficient lead atom while inhibited the migration of halide ions. The outcome of this innovative approach was the realization of an efficient perovskite LED that emitted light at a stable wavelength of 483 nm. The LED exhibited a commendable external quantum efficiency (EQE) of 16.58%, with a peak EQE reaching 18.65%. Through optical coupling enhancement, the EQE was further boosted to 28.82%.[153]
Red PeLEDs
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One of the most crucial aspects of lighting and display technology is the efficient generation of red emission. Quasi-2D perovskites have demonstrated potential for high emission efficiency due to robust carrier confinement. However, the external quantum efficiencies (EQE) of most red quasi-2D PeLEDs are not optimal due to different n-value phases within complex quasi-2D perovskite films.
To address this challenge, Jiang et.al[150] published their findings in Advanced Materials on July 20, 2022. Their research focused on strategically incorporating large cations to enhance the efficiency of red light perovskite LEDs. By introducing phenethylammonium iodide (PEAI)/3-fluorophenylethylammonium iodide (m-F-PEA) and 1-naphthylmethylammonium iodide (NMAI), they achieved precise control over the phase distribution of quasi-2D perovskite materials. This approach effectively reduced the prevalence of smaller n-index phases and concurrently addressed lead and halide defects in the perovskite films. The outcome of this research was the development of perovskite LEDs capable of achieving an EQE of 25.8% at 680 nm, accompanied by a peak brightness of 1300 cd/m2.[150]
White PeLEDs
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High-performance white perovskite LED with high light extraction efficiency can be constructed through near-field optical coupling.[154] The near-field optical coupling between blue perovskite diode and red perovskite nanocrystal was achieved by a reasonably designed multi-layer translucent electrode (LiF/Al/Ag/LiF). The red perovskite nano-crystalline layer allows the waveguide mode and surface plasmon polarization mode captured in the blue perovskite diode to be extracted and converted into red light emission, increasing the light extraction efficiency by 50%. At the same time, the complementary emission spectra of blue photons and down-converted red photons contribute to the formation of white LEDs. Finally, the off-device quantum efficiency exceeds 12%, and the brightness exceeds 2000cd/m2, which are both the highest in white PeLEDs.[154]
Lifetime
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Preparing high-quality all-inorganic perovskite films through solution-based methods remains a formidable challenge, primarily attributed to the rapid and uncontrollable crystallization of such materials. The key innovation involved controlling the crystal orientation of the all-inorganic perovskite along the (110) plane through a low-temperature annealing process (35-40°C). This precise control led to the orderly stacking of crystals, which significantly increased surface coverage and reduced defects within the material. After thorough optimization, the well-oriented CsPbBr3 perovskite LED achieved an external quantum efficiency (EQE) of up to 16.45%, a remarkable brightness of 79,932 cd/m2, and a lifespan of 136 hours when initially operated at a brightness level of 100 cd/m2.[155]
On September 20, 2021, the team led by Sargent et.al[156] from the University of Toronto published their research findings in the Journal of the American Chemical Society (JACS) on bright and stable light-emitting diodes (LEDs) based on perovskite quantum dots within a perovskite matrix. The research reported that perovskite quantum dots remain stable in a precursor solution thin film of perovskite and drive the uniform crystallization of the perovskite matrix using strain quantum dots as nucleation centers. The type I band alignment ensures that quantum dots act as charge acceptors and radiative emitters.[156]
The new material exhibits suppressed biexciton Auger recombination and bright luminescence even at high excitation (600 W/cm2). The red LEDs based on the new material demonstrate an external quantum efficiency of 18% and maintain high performance at a brightness exceeding 4700 cd/m2. The new material extends the LED's operating half-life to 2400 hours at an initial brightness of 100 cd/m2.[156]
Types
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LEDs are produced in a variety of shapes and sizes. The color of the plastic lens is often the same as the actual color of light emitted, but not always. For instance, purple plastic is often used for infrared LEDs, and most blue devices have colorless housings. Modern high-power LEDs such as those used for lighting and backlighting are generally found in surface-mount technology (SMT) packages (not shown).LEDs are made in different packages for different applications. A single or a few LED junctions may be packed in one miniature device for use as an indicator or pilot lamp. An LED array may include controlling circuits within the same package, which may range from a simple resistor, blinking or color changing control, or an addressable controller for RGB devices. Higher-powered white-emitting devices will be mounted on heat sinks and will be used for illumination. Alphanumeric displays in dot matrix or bar formats are widely available. Special packages permit connection of LEDs to optical fibers for high-speed data communication links.
Miniature
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Image of miniature surface mount LEDs in most common sizes. They can be much smaller than a traditional 5mm lamp type LED, shown on the upper left corner. Very small (1.6×1.6×0.35
mm) red, green, and blue surface mount miniature LED package with gold wire bonding details
These are mostly single-die LEDs used as indicators, and they come in various sizes from 2 mm to 8 mm, through-hole and surface mount packages.[157] Typical current ratings range from around 1 mA to above 20 mA. Multiple LED dies attached to a flexible backing tape form an LED strip light.[citation needed]
Common package shapes include round, with a domed or flat top, rectangular with a flat top (as used in bar-graph displays), and triangular or square with a flat top. The encapsulation may also be clear or tinted to improve contrast and viewing angle. Infrared devices may have a black tint to block visible light while passing infrared radiation.[citation needed]
Ultra-high-output LEDs are designed for viewing in direct sunlight.[citation needed]
5 V and 12 V LEDs are ordinary miniature LEDs that have a series resistor for direct connection to a 5 V or 12 V supply.[citation needed]
High-power light-emitting diodes attached to an LED star base (Luxeon, Lumileds)High-power LEDs (HP-LEDs) or high-output LEDs (HO-LEDs) can be driven at currents from hundreds of mA to more than an ampere, compared with the tens of mA for other LEDs. Some can emit over a thousand lumens.[158][159] LED power densities up to 300 W/cm2 have been achieved. Since overheating is destructive, the HP-LEDs must be mounted on a heat sink to allow for heat dissipation. If the heat from an HP-LED is not removed, the device fails in seconds. One HP-LED can often replace an incandescent bulb in a flashlight, or be set in an array to form a powerful LED lamp.
Some well-known HP-LEDs in this category are the Nichia 19 series, Lumileds Rebel Led, Osram Opto Semiconductors Golden Dragon, and Cree X-lamp. As of September 2009, some HP-LEDs manufactured by Cree now exceed 105 lm/W.[160]
Examples for Haitz's law—which predicts an exponential rise in light output and efficacy of LEDs over time—are the CREE XP-G series LED, which achieved 105 lm/W in 2009[160] and the Nichia 19 series with a typical efficacy of 140 lm/W, released in 2010.[161]
LEDs developed by Seoul Semiconductor can operate on AC power without a DC converter. For each half-cycle, part of the LED emits light and part is dark, and this is reversed during the next half-cycle. The efficiency of this type of HP-LED is typically 40 lm/W.[162] A large number of LED elements in series may be able to operate directly from line voltage. In 2009, Seoul Semiconductor released a high DC voltage LED, named 'Acrich MJT', capable of being driven from AC power with a simple controlling circuit. The low-power dissipation of these LEDs affords them more flexibility than the original AC LED design.[163]
Strip
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This section is an excerpt from LED strip light
Several LED spots being reflected as continuous lighting stripAn LED strip, tape, or ribbon light is a flexible circuit board populated by surface-mount light-emitting diodes (SMD LEDs) and other components that usually comes with an adhesive backing. Traditionally, strip lights had been used solely in accent lighting, backlighting, task lighting, and decorative lighting applications, such as cove lighting.
LED strip lights originated in the early 2000s. Since then, increasedLED strip lights originated in the early 2000s. Since then, increased luminous efficacy and higher-power SMDs have allowed them to be used in applications such as high brightness task lighting, fluorescent and halogen lighting fixture replacements, indirect lighting applications, ultraviolet inspection during manufacturing processes, set and costume design, and growing plants.
Composite image of an11 × 44
LED matrix lapel name tag display using 1608/0603-type SMD LEDs. Top: A little over half of the21 × 86 mm
display. Center: Close-up of LEDs in ambient light. Bottom: LEDs in their own red light.Considerations for use
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Power sources
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Simple LED circuit with resistor for current limitingThe current in an LED or other diodes rises exponentially with the applied voltage (see Shockley diode equation), so a small change in voltage can cause a large change in current. Current through the LED must be regulated by an external circuit such as a constant current source to prevent damage. Since most common power supplies are (nearly) constant-voltage sources, LED fixtures must include a power converter, or at least a current-limiting resistor. In some applications, the internal resistance of small batteries is sufficient to keep current within the LED rating.[citation needed]
Electrical polarity
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Unlike a traditional incandescent lamp, an LED will light only when voltage is applied in the forward direction of the diode. No current flows and no light is emitted if voltage is applied in the reverse direction. If the reverse voltage exceeds the breakdown voltage, which is typically about five volts, a large current flows and the LED will be damaged. If the reverse current is sufficiently limited to avoid damage, the reverse-conducting LED is a useful noise diode.[citation needed]
By definition, the energy band gap of any diode is higher when reverse-biased than when forward-biased. Because the band gap energy determines the wavelength of the light emitted, the color cannot be the same when reverse-biased. The reverse breakdown voltage is sufficiently high that the emitted wavelength cannot be similar enough to still be visible. Though dual-LED packages exist that contain a different color LED in each direction, it is not expected that any single LED element can emit visible light when reverse-biased.[citation needed]
It is not known if any zener diode could exist that emits light only in reverse-bias mode. Uniquely, this type of LED would conduct when connected backwards.
Safety and health
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Certain blue LEDs and cool-white LEDs can exceed safe limits of the so-called blue-light hazard as defined in eye safety specifications such as "ANSI/IESNA RP-27.1–05: Recommended Practice for Photobiological Safety for Lamp and Lamp Systems".[171] One study showed no evidence of a risk in normal use at domestic illuminance,[172] and that caution is only needed for particular occupational situations or for specific populations.[173] In 2006, the International Electrotechnical Commission published IEC 62471 Photobiological safety of lamps and lamp systems, replacing the application of early laser-oriented standards for classification of LED sources.[174]
While LEDs have the advantage over fluorescent lamps, in that they do not contain mercury, they may contain other hazardous metals such as lead and arsenic.[175]
In 2016 the American Medical Association (AMA) issued a statement concerning the possible adverse influence of blueish street lighting on the sleep-wake cycle of city-dwellers. Industry critics claim exposure levels are not high enough to have a noticeable effect.[176]
Advantages
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Disadvantages
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Manufacturing
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LED manufacturing involves multiple steps, including epitaxy, chip processing, chip separation, and packaging.[196]
In a typical LED manufacturing process, encapsulation is performed after probing, dicing, die transfer from wafer to package, and wire bonding or flip chip mounting,[197] perhaps using Indium tin oxide, a transparent electrical conductor. In this case, the bond wire(s) are attached to the ITO film that has been deposited in the LEDs.
Flip chip circuit on board (COB) is a technique that can be used to manufacture LEDs.[198]
Applications
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Daytime running light LEDs of an automobileLED uses fall into five major categories:
Indicators and signs
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The low energy consumption, low maintenance and small size of LEDs has led to uses as status indicators and displays on a variety of equipment and installations. Large-area LED displays are used as stadium displays, dynamic decorative displays, and dynamic message signs on freeways. Thin, lightweight message displays are used at airports and railway stations, and as destination displays for trains, buses, trams, and ferries.
Red and green LED traffic signalsOne-color light is well suited for traffic lights and signals, exit signs, emergency vehicle lighting, ships' navigation lights, and LED-based Christmas lights
Because of their long life, fast switching times, and visibility in broad daylight due to their high output and focus, LEDs have been used in automotive brake lights and turn signals. The use in brakes improves safety, due to a great reduction in the time needed to light fully, or faster rise time, about 0.1 second faster[citation needed] than an incandescent bulb. This gives drivers behind more time to react. In a dual intensity circuit (rear markers and brakes) if the LEDs are not pulsed at a fast enough frequency, they can create a phantom array, where ghost images of the LED appear if the eyes quickly scan across the array. White LED headlamps are beginning to appear. Using LEDs has styling advantages because LEDs can form much thinner lights than incandescent lamps with parabolic reflectors.
Due to the relative cheapness of low output LEDs, they are also used in many temporary uses such as glowsticks, and throwies. Artists have also used LEDs for LED art.
Lighting
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With the development of high-efficiency and high-power LEDs, it has become possible to use LEDs in lighting and illumination. To encourage the shift to LED lamps and other high-efficiency lighting, in 2008 the US Department of Energy created the L Prize competition. The Philips Lighting North America LED bulb won the first competition on August 3, 2011, after successfully completing 18 months of intensive field, lab, and product testing.[205]
Efficient lighting is needed for sustainable architecture. As of 2011, some LED bulbs provide up to 150 lm/W and even inexpensive low-end models typically exceed 50 lm/W, so that a 6-watt LED could achieve the same results as a standard 40-watt incandescent bulb. The lower heat output of LEDs also reduces demand on air conditioning systems. Worldwide, LEDs are rapidly adopted to displace less effective sources such as incandescent lamps and CFLs and reduce electrical energy consumption and its associated emissions. Solar powered LEDs are used as street lights and in architectural lighting.
The mechanical robustness and long lifetime are used in automotive lighting on cars, motorcycles, and bicycle lights. LED street lights are employed on poles and in parking garages. In 2007, the Italian village of Torraca was the first place to convert its street lighting to LEDs.[206]
Cabin lighting on recent[when?] Airbus and Boeing jetliners uses LED lighting. LEDs are also being used in airport and heliport lighting. LED airport fixtures currently include medium-intensity runway lights, runway centerline lights, taxiway centerline and edge lights, guidance signs, and obstruction lighting.
LEDs are also used as a light source for DLP projectors, and to backlight newer LCD television (referred to as LED TV), computer monitor (including laptop) and handheld device LCDs, succeeding older CCFL-backlit LCDs although being superseded by OLED screens. RGB LEDs raise the color gamut by as much as 45%. Screens for TV and computer displays can be made thinner using LEDs for backlighting.[207]
LEDs are small, durable and need little power, so they are used in handheld devices such as flashlights. LED strobe lights or camera flashes operate at a safe, low voltage, instead of the 250+ volts commonly found in xenon flashlamp-based lighting. This is especially useful in cameras on mobile phones, where space is at a premium and bulky voltage-raising circuitry is undesirable.
LEDs are used for infrared illumination in night vision uses including security cameras. A ring of LEDs around a video camera, aimed forward into a retroreflective background, allows chroma keying in video productions.
LED for miners, to increase visibility inside mines Los Angeles Vincent Thomas Bridge illuminated with blue LEDsLEDs are used in mining operations, as cap lamps to provide light for miners. Research has been done to improve LEDs for mining, to reduce glare and to increase illumination, reducing risk of injury to the miners.[208]
LEDs are increasingly finding uses in medical and educational applications, for example as mood enhancement.[209] NASA has even sponsored research for the use of LEDs to promote health for astronauts.[210]
Data communication and other signalling
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Light can be used to transmit data and analog signals. For example, lighting white LEDs can be used in systems assisting people to navigate in closed spaces while searching necessary rooms or objects.[211]
Assistive listening devices in many theaters and similar spaces use arrays of infrared LEDs to send sound to listeners' receivers. Light-emitting diodes (as well as semiconductor lasers) are used to send data over many types of fiber optic cable, from digital audio over TOSLINK cables to the very high bandwidth fiber links that form the Internet backbone. For some time, computers were commonly equipped with IrDA interfaces, which allowed them to send and receive data to nearby machines via infrared.
Because LEDs can cycle on and off millions of times per second, very high data bandwidth can be achieved.[212] For that reason, visible light communication (VLC) has been proposed as an alternative to the increasingly competitive radio bandwidth.[213] VLC operates in the visible part of the electromagnetic spectrum, so data can be transmitted without occupying the frequencies of radio communications.
Machine vision systems
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Machine vision systems often require bright and homogeneous illumination, so features of interest are easier to process. LEDs are often used.
Barcode scanners are the most common example of machine vision applications, and many of those scanners use red LEDs instead of lasers. Optical computer mice use LEDs as a light source for the miniature camera within the mouse.
LEDs are useful for machine vision because they provide a compact, reliable source of light. LED lamps can be turned on and off to suit the needs of the vision system, and the shape of the beam produced can be tailored to match the system's requirements.
Biological detection
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The discovery of radiative recombination in aluminum gallium nitride (AlGaN) alloys by U.S. Army Research Laboratory (ARL) led to the conceptualization of UV light-emitting diodes (LEDs) to be incorporated in light-induced fluorescence sensors used for biological agent detection.[214][215][216] In 2004, the Edgewood Chemical Biological Center (ECBC) initiated the effort to create a biological detector named TAC-BIO. The program capitalized on semiconductor UV optical sources (SUVOS) developed by the Defense Advanced Research Projects Agency (DARPA).[216]
UV-induced fluorescence is one of the most robust techniques used for rapid real-time detection of biological aerosols.[216] The first UV sensors were lasers lacking in-field-use practicality. In order to address this, DARPA incorporated SUVOS technology to create a low-cost, small, lightweight, low-power device. The TAC-BIO detector's response time was one minute from when it sensed a biological agent. It was also demonstrated that the detector could be operated unattended indoors and outdoors for weeks at a time.[216]
Aerosolized biological particles fluoresce and scatter light under a UV light beam. Observed fluorescence is dependent on the applied wavelength and the biochemical fluorophores within the biological agent. UV induced fluorescence offers a rapid, accurate, efficient and logistically practical way for biological agent detection. This is because the use of UV fluorescence is reagentless, or a process that does not require an added chemical to produce a reaction, with no consumables, or produces no chemical byproducts.[216]
Additionally, TAC-BIO can reliably discriminate between threat and non-threat aerosols. It was claimed to be sensitive enough to detect low concentrations, but not so sensitive that it would cause false positives. The particle-counting algorithm used in the device converted raw data into information by counting the photon pulses per unit of time from the fluorescence and scattering detectors, and comparing the value to a set threshold.[217]
The original TAC-BIO was introduced in 2010, while the second-generation TAC-BIO GEN II, was designed in 2015 to be more cost-efficient, as plastic parts were used. Its small, light-weight design allows it to be mounted to vehicles, robots, and unmanned aerial vehicles. The second-generation device could also be utilized as an environmental detector to monitor air quality in hospitals, airplanes, or even in households to detect fungus and mold.[218][219]
Other applications
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LED costume for stage performers LED wallpaper by MeystyleThe light from LEDs can be modulated very quickly so they are used extensively in optical fiber and free space optics communications. This includes remote controls, such as for television sets, where infrared LEDs are often used. Opto-isolators use an LED combined with a photodiode or phototransistor to provide a signal path with electrical isolation between two circuits. This is especially useful in medical equipment where the signals from a low-voltage sensor circuit (usually battery-powered) in contact with a living organism must be electrically isolated from any possible electrical failure in a recording or monitoring device operating at potentially dangerous voltages. An optoisolator also lets information be transferred between circuits that do not share a common ground potential.
Many sensor systems rely on light as the signal source. LEDs are often ideal as a light source due to the requirements of the sensors. The Nintendo Wii's sensor bar uses infrared LEDs. Pulse oximeters use them for measuring oxygen saturation. Some flatbed scanners use arrays of RGB LEDs rather than the typical cold-cathode fluorescent lamp as the light source. Having independent control of three illuminated colors allows the scanner to calibrate itself for more accurate color balance, and there is no need for warm-up. Further, its sensors only need be monochromatic, since at any one time the page being scanned is only lit by one color of light.
Since LEDs can also be used as photodiodes, they can be used for both photo emission and detection. This could be used, for example, in a touchscreen that registers reflected light from a finger or stylus.[220] Many materials and biological systems are sensitive to, or dependent on, light. Grow lights use LEDs to increase photosynthesis in plants,[221] and bacteria and viruses can be removed from water and other substances using UV LEDs for sterilization.[118] LEDs of certain wavelengths have also been used for light therapy treatment of neonatal jaundice and acne.[222]
UV LEDs, with spectra range of 220 nm to 395 nm, have other applications, such as water/air purification, surface disinfection, glue curing, free-space non-line-of-sight communication, high performance liquid chromatography, UV curing dye printing, phototherapy (295nm Vitamin D, 308nm Excimer lamp or laser replacement), medical/ analytical instrumentation, and DNA absorption.[215][223]
LEDs have also been used as a medium-quality voltage reference in electronic circuits. The forward voltage drop (about 1.7 V for a red LED or 1.2V for an infrared) can be used instead of a Zener diode in low-voltage regulators. Red LEDs have the flattest I/V curve above the knee. Nitride-based LEDs have a fairly steep I/V curve and are useless for this purpose. Although LED forward voltage is far more current-dependent than a Zener diode, Zener diodes with breakdown voltages below 3 V are not widely available.
The progressive miniaturization of low-voltage lighting technology, such as LEDs and OLEDs, suitable to incorporate into low-thickness materials has fostered experimentation in combining light sources and wall covering surfaces for interior walls in the form of LED wallpaper.
A large LED display behind a disc jockey
LED panel light source used in an early experiment on potato growth during Shuttle mission STS-73 to investigate the potential for growing food on future long duration missions
Research and development
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Key challenges
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LEDs require optimized efficiency to hinge on ongoing improvements such as phosphor materials and quantum dots.[224]
The process of down-conversion (the method by which materials convert more-energetic photons to different, less energetic colors) also needs improvement. For example, the red phosphors that are used today are thermally sensitive and need to be improved in that aspect so that they do not color shift and experience efficiency drop-off with temperature. Red phosphors could also benefit from a narrower spectral width to emit more lumens and becoming more efficient at converting photons.[225]
In addition, work remains to be done in the realms of current efficiency droop, color shift, system reliability, light distribution, dimming, thermal management, and power supply performance.[224]
Early suspicions were that the LED droop was caused by elevated temperatures. Scientists showed that temperature was not the root cause of efficiency droop.[226] The mechanism causing efficiency droop was identified in 2007 as Auger recombination, which was taken with mixed reaction.[188] A 2013 study conclusively identified Auger recombination as the cause.[227]
Potential technology
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A new family of LEDs are based on the semiconductors called perovskites. In 2018, less than four years after their discovery, the ability of perovskite LEDs (PLEDs) to produce light from electrons already rivaled those of the best performing OLEDs.[228] They have a potential for cost-effectiveness as they can be processed from solution, a low-cost and low-tech method, which might allow perovskite-based devices that have large areas to be made with extremely low cost. Their efficiency is superior by eliminating non-radiative losses, in other words, elimination of recombination pathways that do not produce photons; or by solving outcoupling problem (prevalent for thin-film LEDs) or balancing charge carrier injection to increase the EQE (external quantum efficiency). The most up-to-date PLED devices have broken the performance barrier by shooting the EQE above 20%.[229]
In 2018, Cao et al. and Lin et al. independently published two papers on developing perovskite LEDs with EQE greater than 20%, which made these two papers a mile-stone in PLED development. Their device have similar planar structure, i.e. the active layer (perovskite) is sandwiched between two electrodes. To achieve a high EQE, they not only reduced non-radiative recombination, but also utilized their own, subtly different methods to improve the EQE.[229]
In the work of Cao et al.,[230] researchers targeted the outcoupling problem, which is that the optical physics of thin-film LEDs causes the majority of light generated by the semiconductor to be trapped in the device.[231] To achieve this goal, they demonstrated that solution-processed perovskites can spontaneously form submicrometre-scale crystal platelets, which can efficiently extract light from the device. These perovskites are formed via the introduction of amino acid additives into the perovskite precursor solutions. In addition, their method is able to passivate perovskite surface defects and reduce nonradiative recombination. Therefore, by improving the light outcoupling and reducing nonradiative losses, Cao and his colleagues successfully achieved PLED with EQE up to 20.7%.[230]
Lin and his colleague used a different approach to generate high EQE. Instead of modifying the microstructure of perovskite layer, they chose to adopt a new strategy for managing the compositional distribution in the device—an approach that simultaneously provides high luminescence and balanced charge injection. In other words, they still used flat emissive layer, but tried to optimize the balance of electrons and holes injected into the perovskite, so as to make the most efficient use of the charge carriers. Moreover, in the perovskite layer, the crystals are perfectly enclosed by MABr additive (where MA is CH3NH3). The MABr shell passivates the nonradiative defects that would otherwise be present perovskite crystals, resulting in reduction of the nonradiative recombination. Therefore, by balancing charge injection and decreasing nonradiative losses, Lin and his colleagues developed PLED with EQE up to 20.3%.[232]
See also
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References
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Further reading
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